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MessagePosté le: Dim 25 Sep - 05:31 (2016)    Sujet du message: Cbz Z Protecting Group For Click Répondre en citant




Cbz Z Protecting Group For Click > bit.ly/2dsRF73







Cbz Z Protecting Group For Click


d680c458d3
Stability.,,T.,,Song,,,,B.-L.,,,2-phenylisopropyl,,,esters,,,can,,,be,,,removed,,,with,,,1%,,,TFA/DCM,,,,conditions,,,that,,,do,,,not,,,affect,,,t-butyl,,,based,,,protecting,,,groups.,,,2003,,,,,68,,,,,4643.,,,,The,,2,6-Cl2Bzl,,protecting,,group,,may,,also,,be,,used,,in,,Fmoc,,chemistry,,to,,produce,,fully,,protected,,peptide,,fragments,,on,,Wang,,resin,,for,,fragment,,condensation,,synthesis.,,The,,,Bzl,,,,4-MeBzl,,,,and,,,4-MeOBzl,,,groups,,,are,,,removed,,,during,,,HF,,,cleavage.,,,1991,,,,32,,,,475-478..,,,Which,,resins,,can,,be,,used,,for,,the,,synthesis,,of,,peptide,,amides?,,Resins,,suitable,,for,,the,,Fmoc-SPPS,,of,,peptide,,amides:,,Fmoc-Rink,,amide,,AM,,resin,,(Fmoc-2,4-dimethoxy-4'-(carboxymethyloxy)-benzhydrylamine,,linked,,to,,Aminomethyl,,resin),,,Tricyclic,,amide,,linker,,resin,,,PAL,,resin,,,Xanthenyl,,linker,,resin,,(Sieber,,amide,,resin).,,Sigma-Aldrich,,,,Products,,,,are,,,,sold,,,,exclusively,,,,through,,,,Sigma-Aldrich,,,,,Inc.,,,,

If,,not,,available,,for,,your,,order,,,the,,ADS,,can,,be,,downloaded,,from,,the,,Bachem,,website,,,www.bachem.com.,,Boc-Tyr(tBu)-OH,,,,is,,,,useful,,,,in,,,,both,,,,Boc,,,,and,,,,Fmoc,,,,chemistries,,,,as,,,,a,,,,derivative,,,,to,,,,attach,,,,N-terminal,,,,tyrosine,,,,residues,,,,to,,,,peptides,,,,for,,,,125I,,,,labeling.,,,,Overkleeft,,,Jan,,W.,,This,,,,side,,,,reaction,,,,is,,,,minimized,,,,with,,,,a,,,,protecting,,,,group,,,,on,,,,the,,,,amide,,,,nitrogen.,,,,Deprotection,,of,,the,,F-Cbz,,group,,is,,achieved,,under,,the,,same,,conditions,,as,,traditional,,Cbz,,such,,as,,hydrogenation,,or,,hydride,,reduction.,,Special,,,protecting,,,groups,,,have,,,been,,,developed,,,for,,,performing,,,on-resin,,,modification,,,of,,,peptides,,,,such,,,as,,,cyclization,,,,labeling,,,or,,,conjugation,,,with,,,lipids,,,or,,,sugars.,,,H-Ala-OMe,,,,,,,,HCl),,,,and,,,,increase,,,,shelf-stability.,,,,The,,,,NO2,,,,group,,,,is,,,,removed,,,,during,,,,HF,,,,cleavage,,,,of,,,,the,,,,peptide,,,,from,,,,the,,,,resin,,,,,but,,,,it,,,,can,,,,undergo,,,,side,,,,reactions,,,,during,,,,cleavage,,,,leading,,,,to,,,,ornithine,,,,residues.,,,,Ornithine,,derivatives,,use,,the,,same,,sidechain,,protecting,,groups,,as,,lysine.,,For,,,,Boc,,,,chemistry,,,,,the,,,,thiol,,,,moiety,,,,in,,,,the,,,,penicillamine,,,,side,,,,chain,,,,is,,,,protected,,,,with,,,,the,,,,4-MeBzl,,,,group,,,,[Boc-Pen(pMeBzl)-OH].,,,,

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